All measurements so far have been taken with a multimeter on volts DC.
When measuring the power and grounds, the key position doesn’t matter.
However, when measuring the CAN bus voltage, the key must be in the run position.
Unfortunately, I am not familiar with the CAN Bus topology layout on the 3rd Gens.
Looking at the limited information in the manual, it appears that the TIPM is the gateway, and you should be able to communicate with it directly from the OBD port.
The voltage checks on pins#6  with the key in the run position will at least verify that the OBD is connected and communicating with the TIPM.
It appears that the TIPM is the hub for the CAN bus and transmits to the ECM and other modules.
You may be unable to communicate with the ECM because of a failure in the TIPM.
https://tipmrebuilders.com/chrysler-...-tipm-failure/
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